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 | Acesso ao texto completo restrito à biblioteca da Embrapa Pecuária Sudeste. Para informações adicionais entre em contato com cppse.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Pecuária Sudeste. |
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Data corrente: |
17/12/2019 |
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Data da última atualização: |
17/12/2019 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
NEIVA, A. M.; SPERANÇA, M. A.; COSTA, V. C.; JACINTO, M. A. C.; PEREIRA-FILHO, E. R. |
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Afiliação: |
Ariane Maciel Neiva, UFSCar; Marco Aurélio Sperança, UFSCar; Vinicius Câmara Costa, UFSCar; MANUEL ANTONIO CHAGAS JACINTO, CPPSE; Edenir Rodrigues Pereira-Filho, UFSCar. |
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Título: |
Determination of toxic metals in leather by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) with emphasis on chromium. |
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Ano de publicação: |
2018 |
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Fonte/Imprenta: |
Environmental Monitoring and Assessment, v.190, n.168, p.1-15, 2018. |
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DOI: |
https://doi.org/10.1007/s10661-018-6990-y |
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Idioma: |
Inglês |
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Conteúdo: |
The tanning industry is one of the largest environmental polluters due to high generation waste in all production processes, but the tanning is particularly worrisome due to the use of significant amounts of chromium. Cr is an element potentially toxic to both health and the environment, depending on the concentration and the oxidation state. Cr(VI) can come in contact with human skin when using leather goods, which can cause allergies and dermatitis, besides being carcinogenic. Considering that approximately 90% of the world production of leather is performed with Cr salts, the determination of this element in leather is necessary to avoid exposure to the risks that the element can provide. The main goal of this study was the development of an alternative analytical method for the determination of Cr in leathers (ovine and bovine leather tanned with Cr and vegetable tannin) using wavelength dispersive X-ray fluorescence (WDXRF) for direct solid analysis. Besides performing analysis of the chemical composition and determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Ni, Pb, Sb, Sr, Ti, and Zn in leather by inductively coupled plasma optical emission spectrometry (ICP OES). Principal component analysis (PCA) was also used in the evaluation of the WDXRF and ICP OES data sets. WDXRF calibration models for Cr presented satisfactory figures of merit and the analysis of the leathers revealed an alarming concentration of total Cr in the samples reaching 21,353 mg kg?1. |
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Palavras-Chave: |
Cr; Direct solid analysis; Inductively coupled plasma atomic emission spectrometry (ICP OES); Laser-induced breakdown spectroscopy (LIBS); Wavelength dispersive X-ray fluorescence (WDXRF). |
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Thesaurus Nal: |
Leather. |
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Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
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Marc: |
LEADER 02474naa a2200253 a 4500
001 2117090
005 2019-12-17
008 2018 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1007/s10661-018-6990-y$2DOI
100 1 $aNEIVA, A. M.
245 $aDetermination of toxic metals in leather by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) with emphasis on chromium.$h[electronic resource]
260 $c2018
520 $aThe tanning industry is one of the largest environmental polluters due to high generation waste in all production processes, but the tanning is particularly worrisome due to the use of significant amounts of chromium. Cr is an element potentially toxic to both health and the environment, depending on the concentration and the oxidation state. Cr(VI) can come in contact with human skin when using leather goods, which can cause allergies and dermatitis, besides being carcinogenic. Considering that approximately 90% of the world production of leather is performed with Cr salts, the determination of this element in leather is necessary to avoid exposure to the risks that the element can provide. The main goal of this study was the development of an alternative analytical method for the determination of Cr in leathers (ovine and bovine leather tanned with Cr and vegetable tannin) using wavelength dispersive X-ray fluorescence (WDXRF) for direct solid analysis. Besides performing analysis of the chemical composition and determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Ni, Pb, Sb, Sr, Ti, and Zn in leather by inductively coupled plasma optical emission spectrometry (ICP OES). Principal component analysis (PCA) was also used in the evaluation of the WDXRF and ICP OES data sets. WDXRF calibration models for Cr presented satisfactory figures of merit and the analysis of the leathers revealed an alarming concentration of total Cr in the samples reaching 21,353 mg kg?1.
650 $aLeather
653 $aCr
653 $aDirect solid analysis
653 $aInductively coupled plasma atomic emission spectrometry (ICP OES)
653 $aLaser-induced breakdown spectroscopy (LIBS)
653 $aWavelength dispersive X-ray fluorescence (WDXRF)
700 1 $aSPERANÇA, M. A.
700 1 $aCOSTA, V. C.
700 1 $aJACINTO, M. A. C.
700 1 $aPEREIRA-FILHO, E. R.
773 $tEnvironmental Monitoring and Assessment$gv.190, n.168, p.1-15, 2018.
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Embrapa Pecuária Sudeste (CPPSE) |
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| Registros recuperados : 7 | |
| 3. |  | NUNES, W. A. G. de A.; OLIVEIRA, A. dos S.; NEIVA, A. M. Efeito da aplicação de fertilizante orgânico sobre o crescimento de plantas de Eucalyptus urograndis. In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 30.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 14.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 12.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 9.; SIMPÓSIO SOBRE SELÊNIO NO BRASIL, 1., 2012, Maceió. A responsabilidade socioambiental da pesquisa agrícola: anais. Viçosa: SBCS, 2012. Fertbio. Organizado por Leila Cruz da Silva, Gilson Moura Filho, Adriano Barboza Moura, Abel Washington de Albuquerque. 4 p.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Agropecuária Oeste. |
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| 7. | | NEIVA, A. M.; NUNES, W. A. G. de A.; LÁZARI, G. G. de; CAPATO, C. F.; NARCELLI, J. V.; SILVA, W. M. Estudo do potencial de uso agrícola de resíduos de curtume. In: JORNADA DE INICIAÇÃO À PESQUISA DA EMBRAPA, 2012, Dourados. Resumos... Brasília, DF: Embrapa; Dourados: Embrapa Agropecuária Oeste, 2012. 1 CD-ROM. JIPE 2012.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Agropecuária Oeste. |
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| Registros recuperados : 7 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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